Naming Compounds

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🧪 Chemical Bonding: Naming Compounds

The Name Game: How Chemists Talk to Each Other

Imagine you have a toy box full of LEGO pieces. Some are red, some are blue, and some are green. If you build something cool and want to tell your friend about it, you need a name for your creation. You can’t just say “the thing with the pieces” — you need a clear name so your friend knows exactly what you built!

Chemistry works the same way. Scientists have billions of different “LEGO creations” (compounds), and they needed a naming system so everyone around the world understands exactly what compound they’re talking about.


📝 Part 1: Writing Chemical Formulas

What’s a Chemical Formula?

A chemical formula is like a recipe card for a compound. It tells you:

  • Which atoms are in the compound (the ingredients)
  • How many of each atom (the amounts)

The Simple Rules

Think of atoms like friends holding hands:

H₂O = 2 Hydrogen + 1 Oxygen = Water

The subscript number (the tiny number below) tells you how many of that atom.

No number? That means 1 atom!

graph TD A["H₂O"] --> B["H = Hydrogen"] A --> C["2 = Two atoms"] A --> D["O = Oxygen"] A --> E["no number = One atom"]

Writing Formulas for Ionic Compounds

Remember: Ionic compounds are made when a metal gives electrons to a non-metal.

The Golden Rule: The charges must balance to zero!

Think of it like a see-saw. Both sides need to be equal.

Metal Ion Non-metal Ion Formula How?
Na⁺ Cl⁻ NaCl +1 and -1 = 0 ✓
Mg²⁺ Cl⁻ MgCl₂ +2 and 2×(-1) = 0 ✓
Al³⁺ O²⁻ Al₂O₃ 2×(+3) and 3×(-2) = 0 ✓

The Criss-Cross Trick

Here’s a magic shortcut:

  1. Write the two ions with their charges
  2. Criss-cross the numbers (swap them!)
  3. Drop the charges — you have your formula!
graph TD A["Ca²⁺ and Cl⁻"] --> B["Criss-cross the numbers"] B --> C["Ca gets 1, Cl gets 2"] C --> D["CaCl₂ ✓"]

Example: Aluminum oxide

  • Al³⁺ and O²⁻
  • Criss-cross: Al₂O₃
  • Check: 2×(+3) + 3×(-2) = +6 - 6 = 0 ✓

Writing Formulas for Covalent Compounds

Covalent compounds are made when non-metals share electrons — like friends sharing toys!

For these, we use prefixes (number words) to tell us how many atoms:

Prefix Number
mono- 1
di- 2
tri- 3
tetra- 4
penta- 5
hexa- 6

Example: Carbon dioxide

  • “di” means 2 oxygens
  • Formula: CO₂

🏷️ Part 2: Naming Ionic Compounds

The Basic Recipe

Naming ionic compounds is like introducing two friends:

[Metal’s Name] + [Non-metal with -ide ending]

That’s it! Simple as pie! 🥧

graph TD A["NaCl"] --> B["Sodium"] A --> C["Chlorine → Chloride"] B --> D["Sodium Chloride"] C --> D

Examples in Action

Formula Metal Non-metal Name
NaCl Sodium Chlorine → Chloride Sodium chloride
MgO Magnesium Oxygen → Oxide Magnesium oxide
CaBr₂ Calcium Bromine → Bromide Calcium bromide
K₂S Potassium Sulfur → Sulfide Potassium sulfide

Wait! What About Metals That Can’t Make Up Their Mind?

Some metals are like kids who can’t decide how many toys to share. They can have different charges!

Iron (Fe) can be Fe²⁺ OR Fe³⁺ Copper (Cu) can be Cu⁺ OR Cu²⁺

For these wishy-washy metals, we use Roman numerals in parentheses:

Formula Charge Name
FeCl₂ Fe²⁺ Iron(II) chloride
FeCl₃ Fe³⁺ Iron(III) chloride
CuO Cu²⁺ Copper(II) oxide
Cu₂O Cu⁺ Copper(I) oxide

How to Figure Out the Charge

Detective time! 🔍

  1. Look at the non-metal’s charge (you know this!)
  2. Work backwards to find the metal’s charge

Example: What’s the name of CuCl₂?

  • Cl is always -1
  • Two Cl⁻ = total charge of -2
  • So Cu must be +2 to balance!
  • Name: Copper(II) chloride

Naming with Polyatomic Ions

Sometimes, a group of atoms acts like a single ion — like a team!

Common teams you’ll meet:

Polyatomic Ion Charge Example Compound
Hydroxide (OH⁻) -1 NaOH = Sodium hydroxide
Nitrate (NO₃⁻) -1 KNO₃ = Potassium nitrate
Sulfate (SO₄²⁻) -2 CaSO₄ = Calcium sulfate
Carbonate (CO₃²⁻) -2 Na₂CO₃ = Sodium carbonate

The rule stays the same: Metal name + Polyatomic ion name (no change!)


🔗 Part 3: Naming Covalent Compounds

Different Rules for Different Friends

Covalent compounds are formed between two non-metals. Since there’s no metal to name first, we need a new system!

The Prefix System

We use Greek prefixes to count the atoms:

graph TD A["Prefixes"] --> B["mono = 1"] A --> C["di = 2"] A --> D["tri = 3"] A --> E["tetra = 4"] A --> F["penta = 5"] A --> G["hexa = 6"]

The Recipe

[Prefix + First element] + [Prefix + Second element + -ide]

Special rule: We usually skip “mono” on the first element (it sounds weird!)

Let’s Practice!

Formula Name Breakdown
CO Carbon monoxide 1 carbon + 1 oxygen
CO₂ Carbon dioxide 1 carbon + 2 oxygens
N₂O Dinitrogen monoxide 2 nitrogen + 1 oxygen
N₂O₄ Dinitrogen tetroxide 2 nitrogen + 4 oxygens
PCl₃ Phosphorus trichloride 1 phosphorus + 3 chlorines
SF₆ Sulfur hexafluoride 1 sulfur + 6 fluorines

The “a” and “o” Dropping Rule

When a prefix ending in “a” or “o” meets an element starting with “a” or “o”, we drop the extra vowel:

  • “mono” + “oxide” = monoxide (not monooxide)
  • “tetra” + “oxide” = tetroxide (not tetraoxide)

It just sounds better!


🎯 Quick Decision Tree

graph TD A["Is there a METAL?"] -->|Yes| B["IONIC COMPOUND"] A -->|No| C["COVALENT COMPOUND"] B --> D["Metal name + non-metal-IDE"] B --> E["Variable metal? Add Roman numeral"] C --> F["Prefix + element + Prefix + element-IDE"]

💡 Memory Tricks

For Ionic Compounds:

“Metal First, End in -IDE”

  • Sodium + Chlorine = Sodium chloride
  • The metal keeps its name, the non-metal gets an “-ide” makeover!

For Covalent Compounds:

“Count and Convert”

  • Count the atoms
  • Convert the count to Greek prefix
  • CO₂ = 1 Carbon + 2 Oxygen = Carbon dioxide

For Roman Numerals:

“Blame the Metal”

  • If the metal can have different charges, tell everyone which charge with Roman numerals
  • FeCl₃ = Iron(III) chloride (Fe is +3 here)

🌟 Real World Examples

Where You Find It Formula Name Type
Table salt NaCl Sodium chloride Ionic
Baking soda NaHCO₃ Sodium bicarbonate Ionic
Rust Fe₂O₃ Iron(III) oxide Ionic
Car exhaust CO Carbon monoxide Covalent
Fizzy drinks CO₂ Carbon dioxide Covalent
Swimming pool Cl₂ - (element, not compound) -

🎉 You Did It!

You now know how to:

  • Write chemical formulas using the criss-cross method
  • Name ionic compounds (metal + non-metal-ide)
  • Use Roman numerals for metals with multiple charges
  • Name covalent compounds using Greek prefixes

The naming system is like a universal language. A scientist in Japan, a student in Brazil, and a researcher in Germany all know exactly what “sodium chloride” means — it’s NaCl, table salt!

You’re now part of this worldwide conversation. Pretty cool, right? 🧪✨

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